Ideal Gas Equation (PV=nRT) - Universal Gas Constant, Laws & Derivations (2024)

What is Ideal Gas?

An ideal gas is a theoretical gas composed of a set of randomly-moving point particles that interact only through elastic collisions.

The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state and is amenable to analysis under statistical mechanics.

Table of Contents

  • Recommended Videos
  • Ideal Gas Laws
  • Ideal Gas Equation
  • Universal Gas Constant
  • Derivation of the Ideal Gas Equation
  • Frequently Asked Questions – FAQs

Recommended Videos

Ideal Gas Equation definitions, derivation

Ideal Gas Equation (PV=nRT) - Universal Gas Constant, Laws & Derivations (1)

Structure of Atom Class 11 Chemistry

Ideal Gas Equation (PV=nRT) - Universal Gas Constant, Laws & Derivations (2)

Gaseous State

Ideal Gas Equation (PV=nRT) - Universal Gas Constant, Laws & Derivations (3)

Ideal Gas Equation & Its Applications

Ideal Gas Equation (PV=nRT) - Universal Gas Constant, Laws & Derivations (4)

Ideal Gas Laws

The laws which deal with ideal gases are naturally called ideal gas laws and the laws are determined by the observational work of Boyle in the seventeenth century and Charles in the eighteenth century.

  • Boyles Law – states that for a given mass of gas held at a constant temperature the gas pressure is inversely proportional to the gas volume.
  • Charles Law – states that for a given fixed mass of gas held at a constant pressure the gas volume is directly proportional to the gas temperature.

Ideal Gas Equation

The Ideal gas law is the equation of state of a hypothetical ideal gas. It is a good approximation to the behaviour of many gases under many conditions, although it has several limitations. The ideal gas equation can be written as

PV = nRT

Where,

  • P is the pressure of the ideal gas.
  • V is the volume of the ideal gas.
  • n is the amount of ideal gas measured in terms of moles.
  • R is the universal gas constant.
  • T is the temperature.

According to the Ideal Gas equation-

The product of Pressure & Volume of a gas bears a constant relation with the product of Universal gas constant, number of moles of gas and temperature.

i.e.

\(\begin{array}{l}pv = nRT\end{array} \)

Universal Gas Constant (R)

R is a universal gas constant and it is the molar equivalent of boltzmann constant having the units of energy increased per temperature per mole. It is denoted by R.

Note: From the SI system the value of the universal gas constant is 8.314 kJ/mole.K

Derivation of the Ideal Gas Equation

Let us consider the pressure exerted by the gas to be ‘p

The volume of the gas be – ‘v

Temperature be – “T”

“n” – be the number of moles of gas

Universal gas constant – R

According to Boyle’s Law,

At constant n & T, the volume bears an inverse relation with the pressure exerted by a gas.

i.e.

\(\begin{array}{l}v \propto \frac{1}{p}\end{array} \)

………………………………(i)

According to Charles’ Law,

When p & n are constant, the volume of a gas bears a direct relation with the Temperature.

i.e.

\(\begin{array}{l}v \propto T\end{array} \)

………………………………(ii)

According to Avogadro’s Law,

When p & T are constant, then the volume of a gas bears a direct relation with the number of moles of gas.

i.e.

\(\begin{array}{l}v \propto n\end{array} \)

………………………………(iii)

Combining all the three equations, we have-

\(\begin{array}{l}v \propto \frac{nT}{p}\end{array} \)

or

\(\begin{array}{l}pv = nRT\end{array} \)

where R is the Universal gas constant, which has a value of 8.314 J/mol-K

Frequently Asked Questions – FAQs

Q1

What is ideal gas equation and derive it mathematically?

The ideal gas equation is formulated as: PV = nRT. In this equation, P refers to the pressure of the ideal gas, V is the volume of the ideal gas, n is the total amount of ideal gas that is measured in terms of moles, R is the universal gas constant, and T is the temperature.

Q2

What is meant by ideal gas equation?

An equation that equates the product of the pressure and the volume of one mole of a gas to the product of its thermodynamic temperature and the gas constant. The equation is exact for an ideal gas and is a good approximation for real gases at low pressures. Also called: ideal gas equation, ideal gas law.

Q3

What is ideal gas example?

Many gases such as nitrogen, oxygen, hydrogen, noble gases, some heavier gases like carbon dioxide and mixtures such as air, can be treated as ideal gases within reasonable tolerances over a considerable parameter range around standard temperature and pressure.

Q4

What is an ideal gas explain?

An ideal gas is defined as one in which all collisions between atoms or molecules are perfectly eleastic and in which there are no intermolecular attractive forces. In such a gas, all the internal energy is in the form of kinetic energy and any change in internal energy is accompanied by a change in temperature.

Q5

What are ideal gas conditions?

For a gas to be “ideal” there are four governing assumptions: The gas particles have negligible volume. The gas particles are equally sized and do not have intermolecular forces (attraction or repulsion) with other gas particles. The gas particles have perfect elastic collisions with no energy loss.

Ideal Gas Equation (PV=nRT) - Universal Gas Constant, Laws & Derivations (2024)

FAQs

What is the derivation of the ideal gas equation from the gas laws? ›

The ideal gas equation is formulated as: PV = nRT. In this equation, P refers to the pressure of the ideal gas, V is the volume of the ideal gas, n is the total amount of ideal gas that is measured in terms of moles, R is the universal gas constant, and T is the temperature.

What is the answer to derive the ideal gas equation? ›

The Ideal Gas Law equation is PV = nRT, where P is the pressure, V is the volume, 'n' is the number of moles of gas molecules, R is the universal gas constant, and T is the absolute temperature.

What is the ideal gas equation given by PV nRT? ›

The Ideal Gas Law (PV = nRT) is an equation representing the state of a hom*ogenous mixture of gas, which sets variables of that gas's pressure (P) times volume (V) equal to the amount in moles (n) of that gas multiplied by the ideal gas constant (R) multiplied by its temperature (T).

What is the ideal gas law for the ideal gas law constant? ›

The ideal gas law can also be written and solved in terms of the number of moles of gas: PV = nRT, where n is number of moles and R is the universal gas constant, R = 8.31 J/mol ⋅ K.

What is the derivation of the universal gas constant? ›

PV = nRT where n is the number of moles or PV = mRT where m is the mass. It is called the “Universal” Gas Constant because it is constant across all gases. The microscopic kinetic theory also helps us derive the universal gas constant. This was achieved by August Kronig in 1856 and Rudolf Clausius in 1857.

How do you derive the ideal gas constant? ›

The ideal gas law uses the formula PV = nRT where P is the pressure in atmospheres (atm), V is the volume in liters (L), n is the number of moles (mol) and T is the temperature in kelvin (K).

What is the derivation of the ideal gas from the real gas? ›

A real gas in a container of volume V has only available volume of (V - nb) and this can be thought of as an ideal gas in container of volume (V - nb). V = Volume of the gas b = A constant whose value depends upon the nature of the gas.

How to calculate PV nRT? ›

PV=nRT can be written as P=nRT/V. n/V=concentration, so P=conc(RT). Then, you can solve for concentration and then plug that value into K=[P]/[R].

How do you derive Boyle's law from the ideal gas equation? ›

You can derive this from the Combined Gas Equation (P1V1/T1 = P2V2/T2). Since Boyle's law says it is at constant temperature, the temperatures cancel each other so you are left with P1V1 = P2V2 which is Boyle's Law.

How to do the ideal gas equation? ›

Using the Ideal Gas Law Vocabulary and Equations

The equation is given below: P V = n R T In this equation, P is the pressure of the gas, V is the volume, n is the number of moles, and T is the temperature of the gas. R is the "ideal gas constant."

What is the ideal gas law explained? ›

So, in summary, the Ideal Gas Law states that under the same temperature, pressure and volume all gases contain the same number of molecules (but not the same mass). Reminder: The Ideal Gas law does not apply when the temperature and pressure are near the point of transforming into a liquid or solid.

What is the ideal universal gas constant? ›

Summary. The ideal gas constant is calculated to be 8.314J/K⋅mol when the pressure is in kPa. The ideal gas law is a single equation which relates the pressure, volume, temperature, and number of moles of an ideal gas. The combined gas law relates pressure, volume, and temperature of a gas.

How is the ideal gas law derived from the combined gas law? ›

The combined gas law is effectively a restructuring of the ideal gas law, where both n (mols of gas) and R (already a constant) remain constant. It can be used to determine how changes in pressure, volume, or temperature can be used to calculate the conditions of the resulting system.

How do you derive the ideal gas equation using the expression of Boyle's law? ›

From Boyles law P1V1 = P2V; V = P1V1/P2 –––– 1ii Now keeping the pressure of the gas constant at P2. Let the temperature be changed from T1 to T2. Then the volume of the gas changes from V1 to V2.

Which law can be derived from the ideal gas law? ›

The correct answer is d) all of the above: Boyle's law, Charles's law, and Amontons's law can be derived from the Ideal Gas Law. These laws are special cases of the ideal gas law, where two of the four variables (pressure, volume, temperature, and number of moles) are held constant.

References

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